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1.
Ling R. Zeng Li H. Shi Xin G. Meng J. Xu Gui F. Jia T. Gui 《Journal of environmental science and health. Part. B》2019,54(4):317-325
This study evaluated the hydrolysis and photolysis kinetics of pyraclostrobin in an aqueous solution using ultra-high-performance liquid chromatography–photodiode array detection and identified the resulting metabolites of pyraclostrobin by hydrolysis and photolysis in paddy water using high-resolution mass spectrometry coupled with liquid chromatography. The effect of solution pH, metal ions and surfactants on the hydrolysis of pyraclostrobin was explored. The hydrolysis half-lives of pyraclostrobin were 23.1–115.5?days and were stable in buffer solution at pH 5.0. The degradation rate of pyraclostrobin in an aqueous solution under sunlight was slower than that under UV photolysis reaction. The half-lives of pyraclostrobin in a buffer solution at pH 5.0, 7.0, 9.0 and in paddy water were less than 12?h under the two light irradiation types. The metabolites of the two processes were identified and compared to further understand the mechanisms underlying hydrolysis and photolysis of pyraclostrobin in natural water. The extracted ions obtained from paddy water were automatically annotated by Compound Discoverer software with manual confirmation of their fragments. Two metabolites were detected and identified in the pyraclostrobin hydrolysis, whereas three metabolites were detected and identified in the photolysis in paddy water. 相似文献
2.
建立了土壤和沉积物中8种多溴联苯醚(PBDEs,BDE-28、BDE-47、BDE-99、BDE-100、BDE-153、BDE-154、BDE-183和BDE-209)加速溶剂同时萃取和净化-气相色谱-三重四极杆串联质谱(ASE-GC-MS-MS)的分析方法。通过优化加速溶剂萃取与弗罗里硅土在线净化和串联质谱多反应监测模式的条件,较好地去除基质干扰,并提高了三重四极杆串联质谱定性的准确性及定量的灵敏性。该方法采用改进的色谱柱能同时分析包括高溴代联苯醚BDE-209在内的8种PBDEs,其浓度范围为1~100 ng/mL(BDE-209为10~1 000 ng/mL),线性良好,线性回归系数均大于0.997。方法检出限为0.004~0.1 ng/g,方法回收率为75%~110%,方法精密度为2.4%~15.6%。适于批量处理土壤和沉积物中含有多组分痕量PBDEs的样品。 相似文献
3.
In an attempt to identify the ionic imbalance, hydrogen carbonate, HCO3− (bicarbonate), was determined together with the commonly determined nine major ions because the imbalance was frequently encountered in the chemical analysis of samples with high pHs. Titration method was applied for the determination of the samples with pH higher than 5.6. These samples amounted to 102 of the 1536 samples collected in Hokkaido, Northern Japan, from April 1998 to December 2002. Of the 102 samples, 74 (Group A) showed an acceptable ion balance without including HCO3−. In the other 28 (Group B), however, inclusion of HCO3− successfully improved the ion balance. These results suggested that hydrogen carbonate was a potential candidate for explaining the imbalance. The hydrogen carbonate concentrations showed a strong correlation with the corresponding non-sea salt calcium (nss-Ca2+) concentrations, which implied that hydrogen carbonate was derived from calcium carbonate particles incorporated into falling raindrops or cloud droplets. For Group A, the relationship between hydrogen carbonate and the nss-calcium ion concentration was very similar to that for commonly suspended particles in Hokkaido. On the other hand, Group B exhibited a stronger but significantly different correlation. To the samples of Group B, a back-trajectory analysis was applied to demonstrate that the samples were associated with aerosol travelling from Northern China or Mongolia, which indicated that alkaline aerosol affected the chemistry. In consideration of these findings, the current standard of the ion balance should be critically reviewed for modification in regard to the contribution of hydrogen carbonate not only in source areas but also in receptor areas of alkaline aerosol. 相似文献
4.
全面论述了大气气溶胶对环境造成的影响、乌鲁木齐市大气气溶胶的研究现状以及国内外的研究现状,并且对乌鲁木齐市大气气溶胶的进一步研究提出了设想。 相似文献
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6.
Monitoring of ambient PM10 (particulate matter which passes through a size selective impactor inlet with a 50% efficiency cut-off at 10 μm aerodynamic diameter) has been done at residential (Kasba) and industrial (Cossipore) sites of an urban region of Kolkata during November 2003 to November 2004. These sites were selected depending on the dominant anthropogenic activities. Metal constituents of atmospheric PM10 deposited on glass fibre filter paper were estimated using Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES). Chromium (Cr), zinc (Zn), lead (Pb), cadmium (Cd), nickel (Ni), manganese (Mn) and iron (Fe) are the seven toxic trace metals quantified from the measured PM10 concentrations. The 24 h average concentrations of Cr, Zn, Pb, Cd, Ni, Mn and Fe from ninety PM10 particulate samples of Kolkata were found to be 6.9, 506.1, 79.1, 3.3, 7.4, 2.4 and 103.6 ng/m3, respectively. The 24 h average PM10 concentration exceeded national ambient air quality standard (NAAQS) as specified by central pollution control board, India at both residential (Kasba) and industrial (Cossipore) areas with mean concentration of 140.1 and 196.6 μg/m3, respectively. A simultaneous meteorology study was performed to assess the influence of air masses by wind speed, wind direction, rainfall, relative humidity and temperature. The measured toxic trace metals generally showed inverse relationship with wind speed, relative humidity and temperature. Factor analysis, a receptor modeling technique has been used for identification of the possible sources contributing to the PM10. Varimax rotated factor analysis identified four possible sources of measured trace metals comprising solid waste dumping, vehicular traffic with the influence of road dust, road dust and soil dust at residential site (Kasba), while vehicular traffic with the influence of soil dust, road dust, galvanizing and electroplating industry, and tanning industry at industrial site (Cossipore). 相似文献
7.
Mamoru Morikawa Kazutoshi Cho Soromon Kataoka Emi H. Kato Takashi Yamada Hideto Yamada Hisanori Minakami 《黑龙江环境通报》2005,25(3):250-252
Two cases with a large cystic mass within the placenta are reported. By ultrasonography, it was found that both women had a subchorionic hypoechoic lesion (11.0 × 4.8 × 4.0 cm and 6.6 × 3.7 × 2.2 cm, respectively) at 24 and 35 weeks of gestation, respectively. In both cases, turbulent blood flow generated by a pulsatile jet flow (pulse rate; 40 to 60 beats per minute) into the cystic lesion seen on real-time imaging and lesions being low intensity on T1-weighted and isointensity on T2-weighted magnetic resonance image suggested that they contained fresh maternal blood. In both cases, the sonolucency of the lesions did not change until cesarean deliveries of females, both of whom were small-for-gestational-age infants (1940 g at 37 weeks and 2195 g at 37 weeks, respectively). Biochemical analysis of the fluid in the cystic lesion sampled during the cesarean section in the latter case confirmed that the fluid had originated from the maternal blood. These lesions histologically corresponded to large avillous areas surrounded by normal villi. Thus, a huge placental lake was diagnosed in both cases. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
8.
卫星遥感气溶胶虽然空间覆盖度高,但不同产品数据在准确性和适用性上存在显著差异.为了能够科学定量的衡量各个产品的优劣,选择最合适的气溶胶产品,该研究以数学统计为基础,提出了一种卫星遥感气溶胶产品评估体系,并依此确定了全球6个人口密集地区的最优卫星数据集,在此基础上开展了近10年的(2009—2018)气溶胶时空变化分析.结果表明暗像元算法在植被覆盖度高的地区表现最好,深蓝算法在亮地表的沙漠干旱地区更占优势,而暗像元-深蓝融合算法在土地类型复杂且气溶胶来源多变时得以突出.人口密集的6个区域中,除了区域A和区域B,其它地区的大气污染水平整体偏高.其中,A、B、E的气溶胶负荷呈下降变化,区域F基本不变,其余区域上升变化.评估体系的建立为气溶胶遥感产品的选取提供了新的衡量方法,且该文关于气溶胶时空分布及变化的分析可以为区域性气溶胶研究提供一定的参考价值. 相似文献
9.
采集太原市城北和城南区域环境空气和5类污染源挥发性有机物样品,测定样品中典型单环芳烃稳定氢同位素(δD)组成,基于同位素质量平衡原理计算单环芳烃从源到环境空气受体的δD初始混合值,探讨单环芳烃来源.结果表明,柴油挥发源、溶剂挥发源、汽油挥发源(97#)、汽油挥发源(95#)、机动车尾气(97#)、机动车尾气(95#)和民用燃煤源中单环芳烃δD范围依次为:(-138.7‰~-115.5‰)、(-147.0‰~-121.0‰)、(-150.8‰~-117.6‰)、(-131.8‰~-113.8‰)、(-171.2‰~-120.0‰)、(-138.9‰~-102.7‰)和(-168.3‰~-142.3‰),民用燃煤源中单环芳烃δD显著贫重氢同位素(D)组成,机动车尾气源与汽油挥发源中苯的δD相比显著贫D,可用于探索污染物转化过程;城北和城南环境空气中δD范围为(-131.7‰~-115.1‰)和(-131.9‰~-74.9‰),δD初始混合值为-138.4‰和-173.9‰,体现了其来源差异. 相似文献
10.
基于臭氧监测仪(OMI)卫星反演数据,对2005~2018年西北4省区域大气甲醛柱浓度数据进行提取及分析,探讨其时空变化特征及影响因素.结果表明:在时间变化上,14a甲醛柱浓度整体呈先上升后下降的波动变化趋势,夏秋季显著高于冬春季,且冬季均值略高于春季.在空间分布上,甲醛柱浓度自西向东、自北向南逐渐升高,高值区集中于陕西和甘肃东南部及青海西南部;低值区集中于宁夏、青海和甘肃的西北部;稳定性呈现出东部分散、西部集聚、差异显著的分布格局.影响甲醛柱浓度变化的因素包括自然和人为因素,自然因素中,甲醛柱浓度受地形影响显著,与风向、气温均呈现显著正相关;人为因素中,甲醛柱浓度与人口密度、地区生产总值、工业废气排放量及建筑房屋竣工面积均表现出正相关关系,与工业废气排放量的相关度最高.大气中甲醛分子与气溶胶粒子二者间呈显著正相关关系,这进一步说明甲醛浓度受到了诸多因素的综合影响,但气溶胶粒子、气温及工业废气的排放是主导因素. 相似文献